Dental Composite Resin: What is it?

 

Composite resin is a tooth-coloured material used in dentistry for restoring decayed, chipped, or fractured teeth. It’s a blend of synthetic resins and finely ground glass-like particles that mimics the appearance of natural teeth. Known for its aesthetic and functional qualities, it is commonly used in fillings, veneers, and cosmetic bonding procedures.

History of Composite Resin

Composite resins have come a long way since their introduction in the 1960s. Their development can be divided into three significant periods, each marked by advancements in their formulation and clinical application.

The Traditional Period

The earliest composite resins were based on macrofilled particles. While they offered decent strength, they lacked polishability and tended to wear down or discolour over time.

The Microfilled Period

Introduced in the late 1970s, microfilled composites included much smaller filler particles. These improved the polishability and aesthetics but were less durable for load-bearing areas.

The Hybrid Period

The hybrid era combined the strengths of macrofilled and microfilled resins. These materials offered both strength and aesthetics, making them suitable for a broader range of restorative procedures.

Composition of Dental Composites

Dental composite resins are engineered materials composed of several key components that work together to achieve optimal mechanical strength, polishability, and biocompatibility.

Resin Matrix

The organic matrix is primarily composed of monomers such as Bis-GMA (bisphenol A-glycidyl methacrylate), UDMA (urethane dimethacrylate), and TEGDMA (triethylene glycol dimethacrylate). These monomers polymerise under light activation, forming a rigid network.

  • Bis-GMA: Offers high viscosity and strength.

  • TEGDMA: Used to dilute the highly viscous Bis-GMA, improving flow but increasing polymerisation shrinkage.

  • UDMA: An alternative to Bis-GMA with lower viscosity and improved mechanical properties.

Inorganic Filler Particles

These are added to reinforce the resin matrix and improve physical characteristics such as wear resistance, radiopacity, and reduced polymerisation shrinkage. Common fillers include:

Silica (SiO₂)

Glass ceramics (e.g., barium or strontium glass for radiopacity)

Zirconia-silica composites
The size, shape, and distribution of these particles determine the composite’s classification—such as microfilled, nanofilled, or hybrid—and influence surface smoothness and polish retention.

Coupling Agent

A silane coupling agent is used to chemically bond the inorganic fillers to the organic matrix. This bond is essential to ensure stress transfer between the matrix and fillers, enhancing durability and resistance to microfractures.

Photoinitiators

Typically, camphorquinone is the primary photoinitiator used in light-cured composites. When exposed to blue light (approx. 468 nm), it activates the polymerisation process by reacting with amine accelerators to form free radicals.

Additives and Pigments

  • Inhibitors (e.g., butylated hydroxytoluene or BHT) are included to control storage stability and prevent premature polymerisation.

  • Pigments and opacifiers are added to match the composite’s colour to natural teeth (A-D shades), improving aesthetics.

  • Fluoride-releasing agents may also be included in some composites for anti-cariogenic benefits.

This intricate combination of ingredients allows dental composites to be tailored to various clinical needs, from anterior restorations requiring high aesthetics to posterior fillings that demand mechanical strength.

Composite Resin Filler Types and Particle Size

Fillers vary in size and type. The size affects the polishability, strength, and wear resistance of the final restoration. Common categories include:

  • Macrofilled: Large particles (8–12 microns)

  • Microfilled: Smaller particles (<1 micron)

  • Nanofilled: Ultra-small particles for superior polish

  • Hybrid: A mix of different sizes for a balance of strength and aesthetics

Why is It Used in Dentistry?

Composite resin has become the preferred restorative material in modern dentistry due to its unique blend of functional, aesthetic, and conservative properties. Its widespread use spans multiple disciplines, including restorative dentistry, cosmetic dentistry, and even prosthodontics.

Conservation of Tooth Structure

One of the core advantages of composite is its ability to adhere micromechanically and chemically to enamel and dentine, allowing for minimally invasive preparations. Unlike amalgam, which requires removal of sound tooth structure to create mechanical undercuts, composites bond directly to the tooth, preserving its natural integrity.

Aesthetic Restoration

Composite resins are available in a wide range of shades and translucencies, mimicking the optical properties of enamel and dentine. They can be layered to replicate the depth and character of natural teeth, making them ideal for anterior restorations, diastema closures, and chipped tooth repair.

Versatility

Composite resins are highly adaptable for both anterior and posterior restorations. They can be used for:

Class I–V cavity restorations

Core build-ups under crowns

Cosmetic veneers

Occlusal recontouring

Root surface restorations

Temporary splints and bite guards

Durability and Wear Resistance

Modern composites, especially nano-hybrids, offer significantly improved wear resistance, fracture toughness, and compressive strength, making them suitable for high-load areas such as molars.

Biocompatibility

Composites are generally well-tolerated by soft tissues and do not contain mercury, unlike amalgam. Although rare cases of sensitivity to monomers exist, these are typically manageable with careful material selection and technique.

Repairability and Easy Maintenance

Composite restorations can be easily repaired or modified by roughening the surface and adding fresh material. This makes them ideal for situations where gradual adjustments or aesthetic enhancements are needed over time.

Advantages of Composite Resin Filling

  • Matches the natural tooth shade

  • Requires minimal tooth removal

  • Bonds strongly to the tooth structure

  • Sets quickly with curing light

  • Mercury-free alternative to amalgam

Disadvantages of Composite Resin Filling

  • May wear faster than metal fillings

  • Slightly more technique-sensitive

  • Prone to staining over time

  • Can shrink slightly during setting, potentially affecting margins

Direct Dental Composite

Direct composite application is the most common and clinically versatile method for placing composite resin restorations. In this approach, the composite material is applied, shaped, and cured directly inside the patient’s mouth, making it ideal for chairside procedures completed in a single visit.

Step-by-Step Clinical Procedure

Cavity Preparation or Surface Cleaning

The process begins with the preparation of the tooth. For carious lesions, the decayed portion is removed conservatively. In cosmetic applications (e.g., veneers or diastema closures), only minimal or no tooth structure may need alteration. The focus is always on preserving as much natural enamel as possible.

Etching

A 35–37% phosphoric acid gel is applied to the enamel and, in many cases, the dentine for 10–15 seconds. This creates microporosities in the tooth surface, increasing surface area and allowing for micromechanical retention of the adhesive.

Rinsing and Drying

The acid is thoroughly rinsed off, and the tooth is lightly dried. Overdrying the dentine should be avoided to prevent collagen fibre collapse, which could compromise the bond.

Bonding Agent Application

A dental adhesive (bonding agent) is applied to the etched surfaces. It penetrates the microporosities and, once cured with a light-curing unit, forms a hybrid layer that serves as a foundation for the composite resin.

Incremental Composite Placement

The composite resin is applied in increments (typically 2 mm or less) to minimise polymerisation shrinkage, which can lead to marginal gaps and postoperative sensitivity. Each layer is sculpted to the desired anatomy before being light-cured.

Light Curing

Each increment is cured with a high-intensity curing light (LED or halogen) for 10–40 seconds, depending on the material thickness, opacity, and manufacturer guidelines. Proper curing is essential for achieving full polymerisation and optimal physical properties.

Finishing and Polishing

Once all layers are cured and the final anatomy is sculpted, the restoration is finished using fine diamond burs, abrasive discs, and polishing pastes. A high-quality polish improves aesthetics and reduces plaque accumulation, increasing the longevity of the restoration.

Setting Mechanism of Composite Filling

As there are different types of composite resin materials, they require different setting mechanisms, such as: 

Chemical Cure / Self-cure

This type of composite resin hardens through a chemical reaction when two components are mixed. It sets without external light, making it useful for areas with limited access.

Light Cure

Light-cure composites harden when exposed to a specific wavelength of light, typically blue LED. This allows better control over working time and precise placement.

Dual Cure 

Dual-cure composites combine both chemical and light-curing mechanisms. They offer the flexibility of light activation with the assurance of chemical setting in deeper or obscured areas.

Classification of Resin-based Dental Composites

Indirect Dental Composite

In this method, the restoration is fabricated outside the mouth, such as in a lab, and later bonded to the tooth. It’s typically used for inlays, onlays, and crowns where enhanced durability is needed.

Bonding Mechanism

Before applying the composite, the tooth surface is treated with a bonding agent that creates micro-mechanical retention. This helps the composite adhere securely to the enamel or dentin, enhancing durability and resistance to leakage.

Comparison Between Composite Resin and Dental Amalgam

Feature

Composite Resin

Dental Amalgam

Appearance

Tooth-coloured

Metallic (silver)

Bonding

Bonds to tooth

Requires undercuts

Mercury Content

Mercury-free

Contains mercury

Durability

Good, especially newer types

Longer-lasting in some cases

Application

More technique-sensitive

Easier to apply

Ask About Composite Treatment in Melbourne? 

Interested in restoring your smile with composite resin or composite veneers? Whether you need a cosmetic enhancement or a reliable filling, composite treatments offer a natural look with lasting performance. Speak to our cosmetic dentist in Melbourne, fill in our form for a free consultation, and for your composite treatment in Melbourne. 

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